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Paper: The best for red and yellow – a new additive technology for waterborne iron oxide concentrates
In decorative coatings the use of pigment
concentrates is a modern and flexible way to produce colored paints. Especially
in waterborne applications these concentrates have to be compatible with a
broad range of different binder technologies. Because of that the concentrate
formulations are usually free of binder and highly compatible.
Furthermore the demands in terms of
storage stability, color strength and cost efficiency are very high. These
demands are directly conferrable to the used additive technology. The additive
has to give outstanding viscosity reduction to achieve highest pigment loads
and most economic grinding, it has to stabilize the pigments over a long period
of time without any change in rheology and it has to develop the color to the
maximum to avoid any waste of expensive pigments.
The most important pigment class in
decorative coatings are the iron oxides. Iron oxides are not difficult to wet
but because of the shape iron oxide yellow tends to give dilatant rheology
which can be a disaster when it comes to automatically dosing in a dispensing
machine. Iron oxide red tends on the other hand to change the color shade over
time.
This article introduces new findings
concerning iron oxide pigments and their use in binder-free pigment
concentrates.
It discusses advantages and disadvantages
of using classical additive technologies for iron oxide pigments. It introduces
a technology that combines a polymeric structure with phosphate groups to
achieve the outstanding viscosity reduction of polyacrylate salts and the long
term stability of high polymeric additives.
In the end advice and guidelines for
formulating iron oxide pigment concentrates is given.